Imidazoline formation
Condenses with fatty acids first to an amide, then with further heating and water removal to a 1-hydroxyethyl-2-alkyl imidazoline.
RCOOH + AEEA → imidazoline + 2 H₂O
2-[(2-Aminoethyl)amino]ethanol · HEEDA · ≥ 99% commercial grade, LR and AR grades
Aminoethylethanolamine combines an ethyleneamine and an ethanolamine in one molecule — a primary amine, a secondary amine and a hydroxyl — and is the standard raw material for imidazoline softeners and corrosion inhibitors, HEDTA chelants and lubricant additives. Chelora Amines supplies it worldwide to fabric-care, oilfield, chelant, lubricant and resin producers across Asia, the Middle East, Africa, Europe and the Americas, as well as throughout India, with a batch-wise COA and SDS on every dispatch.
48.04 + 12.10 + 28.01 + 16.00 = 104.15 g/mol
Aminoethylethanolamine, usually shortened to AEEA and also called HEEDA, N-(2-hydroxyethyl)ethylenediamine or 2-[(2-aminoethyl)amino]ethanol, carries a primary amine, a secondary amine and a primary hydroxyl on a short chain. That makes it more reactive and more versatile than either an ethanolamine or a simple ethyleneamine.
It is a clear, colourless to pale yellow, viscous, hygroscopic liquid with a mild ammoniacal odour, boiling at about 240 °C and miscible with water. It absorbs carbon dioxide and water from the air, so sealed packing and nitrogen blanketing help keep colour and assay stable.
AEEA is made industrially either by reacting ethylenediamine with ethylene oxide, or as a co-product of ethyleneamine manufacture from monoethanolamine and ammonia; it is purified by vacuum distillation. Piperazine-type by-products, especially hydroxyethylpiperazine, are the impurities that specifications control.
| Chemical name | 2-[(2-Aminoethyl)amino]ethanol (aminoethylethanolamine) |
| Common synonyms | Aminoethylethanolamine, AEEA, HEEDA, N-(2-hydroxyethyl)ethylenediamine, hydroxyethylethylenediamine |
| CAS number | 111-41-1 |
| EC / EINECS number | 203-867-5 |
| HS / HSN code | 2922 19 (harmonised heading used worldwide; HSN 2922 19 on Indian invoices) |
| Molecular formula | C₄H₁₂N₂O (H₂NCH₂CH₂NHCH₂CH₂OH) |
| Molecular weight | 104.15 g/mol |
| Appearance | Clear, colourless to pale yellow viscous liquid |
| Odour | Mild, ammoniacal |
| Melting / freezing point | About −28 °C |
| Boiling point | About 240 °C |
| Density | About 1.03 g/cm³ at 20 °C |
| Vapour pressure | Below 0.01 hPa at 20 °C |
| Solubility in water | Completely miscible |
| pH | Strongly alkaline in aqueous solution |
| Flash point | About 135–145 °C (closed cup) |
| Transport | Typically shipped as a Class 8 corrosive (for example UN 3267, PG III) — confirm on the SDS for your batch |
Figures are typical literature values for orientation. Values for the material you order are stated on its Certificate of Analysis and Safety Data Sheet.
Two different nitrogens and a hydroxyl explain what AEEA is used for: building imidazoline rings, amides and chelants, and curing resins. These are the jobs formulators and process chemists reach for it to do.
Condenses with fatty acids first to an amide, then with further heating and water removal to a 1-hydroxyethyl-2-alkyl imidazoline.
RCOOH + AEEA → imidazoline + 2 H₂OAt lower temperatures with fatty acids it stops at the amidoamine, an intermediate for softeners and asphalt emulsifiers.
RCOOH + AEEA → RCONHCH₂CH₂NHCH₂CH₂OHImidazolines and amidoamines from AEEA are quaternised to make cationic fabric softeners and hair conditioners.
imidazoline + R′X → imidazolinium saltReacts with formaldehyde and cyanide, or chloroacetic acid, to give hydroxyethylethylenediaminetriacetic acid, a chelating agent.
AEEA → HEDTAThe two amine nitrogens react with epoxy groups, so AEEA is used as or in epoxy hardeners and as a resin modifier.
R–NH₂ + epoxide → amino alcoholNeutralises acids and forms salts used in lubricant and fuel additives.
RCOOH + AEEA → saltImidazoline and amidoamine derivatives film metal surfaces, protecting pipelines and equipment in oilfield and refinery systems.
imidazoline film on steelUnder harsh conditions AEEA can cyclise to hydroxyethylpiperazine — the reason specifications cap piperazine-type impurities.
AEEA → HEP + H₂OProcess notes. Imidazoline synthesis needs good water removal and temperature control to convert the amide fully to the ring. AEEA is corrosive and can cause skin sensitisation — keep skin contact to a minimum. Keep drums closed to avoid CO₂ pick-up, which forms carbamate and raises colour.
Discuss your processAEEA is made by two related routes. Both explain why the specification controls piperazine-type by-products, related ethyleneamines, water and colour.
Either ethylenediamine is reacted with ethylene oxide, or monoethanolamine is aminated with ammonia over a catalyst.
The reaction runs under controlled temperature and pressure to favour AEEA over higher products.
The crude contains AEEA with ethyleneamines, hydroxyethylpiperazine and water.
A vacuum distillation train separates AEEA from lighter amines and heavier by-products.
AEEA is tested for purity, piperazines, water and colour, then filled into drums or totes under nitrogen.
The real quality question is "what else came with it". Hydroxyethylpiperazine and other cyclic amines do not form imidazolines properly, and water slows the cyclisation. Related ethyleneamines change the amine value and the product distribution in your reaction.
For softener and corrosion-inhibitor producers, a consistent amine value and low colour matter most. If your process is sensitive, say so at enquiry stage and we will match the batch.
In sealed original packing, stored cool and out of sunlight, AEEA is normally used within twelve months, and we recommend a re-check of assay and colour after that before a critical batch. Air and carbon dioxide ingress form carbamate and raise colour.
Keep drums closed between draws and blanket bulk tanks with dry nitrogen. A retained sample of each batch is held here, so any query can be tested against the original material.
Tell us the application and we will confirm the grade. Commercial grade covers softeners, corrosion inhibitors and chelants; LR and AR grades are available for laboratory work.
The everyday grade for imidazolines, amidoamines, HEDTA and lubricant additives.
Tighter colour and piperazine limits for personal care conditioners and pale softeners.
Tighter limits on related amines and water for R&D and QC.
| Parameter | Test method | Typical specification |
|---|---|---|
| Appearance | Visual | Clear liquid, free from suspended matter |
| Purity (AEEA) | GC | ≥ 99.0 % w/w |
| Hydroxyethylpiperazine | GC | ≤ 0.5 % w/w |
| Water | Karl Fischer | ≤ 0.5 % w/w |
| Colour | APHA | ≤ 30 |
| Density at 20 °C | Densitometer | 1.025 – 1.035 g/cm³ |
Indicative specification for planning. The controlling document is the Certificate of Analysis issued for your batch. If your process needs tighter limits, say so at enquiry stage and we will quote against your specification.
Imidazoline and amidoamine producers choose between AEEA and polyethyleneamines such as DETA. The choice decides whether the product carries a hydroxyethyl or an aminoethyl side chain.
| Point of comparison | AEEA | Diethylenetriamine (DETA) |
|---|---|---|
| Side chain on the imidazoline | Hydroxyethyl | Aminoethyl |
| Best suited to | Fabric softeners, hair conditioners, oilfield corrosion inhibitors | Corrosion inhibitors, epoxy curing agents, polyamides |
| Further reaction after ring closure | Hydroxyl can be esterified or ethoxylated | Free amine can be amidated or quaternised |
| Volatility | Very low | Low |
| Typical colour of products | Paler | Can be darker |
AEEA sits between two better-known products: it carries the hydroxyethyl group of an ethanolamine and the two nitrogens of an ethyleneamine. That combination is why it forms imidazolines so readily.
| Property | Aminoethylethanolamine (AEEA) | Monoethanolamine (MEA) | Ethylenediamine (EDA) |
|---|---|---|---|
| CAS number | 111-41-1 | 141-43-5 | 107-15-3 |
| Formula | H₂NCH₂CH₂NHCH₂CH₂OH | HOCH₂CH₂NH₂ | H₂NCH₂CH₂NH₂ |
| Molecular weight | 104.15 | 61.08 | 60.10 |
| Reactive groups | One primary amine, one secondary amine, one hydroxyl | One primary amine, one hydroxyl | Two primary amines |
| Boiling point | About 240 °C | 170 °C | About 116 °C |
| Volatility and flammability | Very low | Low | Volatile, flammable |
| Typical outlets | Imidazoline softeners and corrosion inhibitors, HEDTA chelant, lubricant and fuel additives | Gas treating, detergent salts, ethanolamides | Chelants (EDTA), epoxy hardeners, fungicides |
Order by full name and CAS. AEEA is also sold as hydroxyethylethylenediamine (HEEDA) or N-(2-hydroxyethyl)ethylenediamine. Write the full chemical name and CAS 111-41-1 on the enquiry and purchase order so it is not confused with ethylenediamine or ethanolamines.
See the full amine rangeMost AEEA goes into imidazoline softeners and corrosion inhibitors, chelants and lubricant additives, with a tail of resin and coating uses. Here is the full picture, sector by sector.
Converted to hydroxyethyl imidazolines and amidoamines, then quaternised into cationic softeners for laundry and textile finishing.
Imidazolines from AEEA film steel surfaces in pipelines, wells and refinery overheads.
The raw material for HEDTA, used to control iron and other metals in cleaners, agriculture and textile processing.
Used to make dispersants, friction modifiers and detergent additives.
Imidazolinium and amidoamine derivatives are used in hair conditioners and amphoteric surfactants.
Used as an epoxy curing agent, resin modifier and in wet-strength and ion-exchange resins.
Amidoamines from AEEA act as cationic asphalt emulsifiers and anti-stripping agents.
A building block for pharmaceutical and agrochemical intermediates that need a diamine with a hydroxyl.
If you are mapping a value chain or looking for the product one step down from where you are, this is where aminoethylethanolamine ends up. Several of these are chemicals we can also source for you.
| Derivative | Made by | End use |
|---|---|---|
| Hydroxyethyl alkyl imidazolines | Condensation with fatty acids and ring closure | Corrosion inhibitors and softener intermediates |
| Imidazolinium quats | Quaternisation of imidazolines | Fabric softeners and hair conditioners |
| Amidoamines | Partial amidation with fatty acids | Softeners, asphalt emulsifiers, amphoteric surfactants |
| HEDTA | Carboxymethylation | Chelating agent for iron and other metals |
| Lubricant and fuel additives | Reaction with acids and anhydrides | Dispersants and friction modifiers |
| Epoxy curing agents and resin modifiers | Reaction with epoxides | Coatings, adhesives and composites |
Looking for one of these rather than the amine itself? Ask us — several are within our sourcing network, and we can quote the derivative and the raw material together.
Every container carries the Chelora Amines label with product name, grade, net weight, batch number, manufacturing date, UN number where applicable and hazard pictograms.

HDPE and MS drums, nitrogen-flushed — the most common pack for AEEA.

Forklift-ready totes with bottom valves for regular users.

500 mL to 25 L packs for laboratory, pilot and qualification work.

Road tankers and ISO tanks for high-volume users.
Share your monthly consumption and the product you make with AEEA, and we will recommend the grade, pack size and delivery schedule that keeps your plant running without excess inventory. Export consignments are packed in UN-specification or export-grade containers, palletised and stretch-wrapped, and shipped FOB, CIF or CFR through Nhava Sheva and Mundra.
Plan my supplyAminoethylethanolamine causes severe skin burns and eye damage, may cause an allergic skin reaction, and carries further health classifications listed on the SDS. The notes below are a summary for planning only — always work to the Safety Data Sheet supplied with your consignment and your own site risk assessment.
Aminoethylethanolamine is typically shipped as a Class 8 corrosive. That is routine for us, but it shapes the packing, labelling and paperwork before a first shipment moves.
| Item | Classification |
|---|---|
| Proper shipping name | Corrosive liquid, basic, organic, n.o.s. (2-(2-aminoethylamino)ethanol) — confirm on the SDS |
| UN number | Typically UN 3267 — confirm on the SDS for your batch |
| Hazard class | Class 8 (corrosive) |
| Packing group | III |
| Labels | Corrosion pictogram |
| Modes | Road, sea (IMDG) and air within dangerous goods quantity limits |
| Segregation | Away from acids, oxidisers and food-grade cargo |
Because AEEA is a dangerous good with health classifications, export bookings need correct UN packaging, labelling and a dangerous goods declaration, and some destinations require importer registration or inventory listing such as REACH. Tell us the destination at enquiry stage and we will confirm what is needed before the shipment is booked.
Start account opening| Parameter | Specification | Result |
|---|---|---|
| Appearance | Clear liquid | Complies |
| Purity (GC) | ≥ 99.0 % | Complies |
| Hydroxyethylpiperazine | ≤ 0.5 % | Complies |
| Water (KF) | ≤ 0.5 % | Complies |
| Colour (APHA) | ≤ 30 | Complies |
Aminoethylethanolamine is checked before dispatch and each consignment leaves with the paperwork your QC, stores and accounts teams need on day one.
The numbers on a Certificate of Analysis are only useful if you know how they were produced. These are the methods behind the figures on ours, and the checks worth repeating at your own goods-inward.
Separates aminoethylethanolamine from the related amines made in the same reactor, and gives the assay and impurity profile that matter most to your formulation.
An independent check on total amine content, useful as a quick goods-inward confirmation before a drum is released to production.
Water determination, which matters for anhydrous grades and confirms strength on aqueous grades.
A visual platinum–cobalt comparison. A rising colour value is the earliest sign that a pack has been exposed to air, heat or held too long.
Fast confirmation that the material is what the label says, and a simple way to spot dilution or the wrong pack.
Titration of total amine value confirms the active content that imidazoline and softener producers dose against.
A sample from every dispatched batch is held here, so a query months later can be settled against the original material rather than an argument.
Batch number on the label ties back to the COA, the test record and the supply lot, which is what your auditor will ask to see.
Where your customer or regulator needs an independent result, we can arrange analysis at a NABL-accredited laboratory before dispatch.
Five steps for a first order of aminoethylethanolamine. Repeat orders follow the same route on a schedule that matches your consumption.
Grade, quantity, pack size and delivery location or destination port.
We confirm the grade for your application and quote, usually within 24 hours.
The batch is tested and the COA, SDS and invoice details are prepared.
Labelled packs move by road, or in export packing for overseas buyers.
Material reaches your gate and repeat dispatches are scheduled to your usage.
Aminoethylethanolamine is a commodity on a price list. What separates suppliers is grade flexibility, the paperwork and the answer you get when something is not routine.
Aminoethylethanolamine sits alongside more than fifty other amines we stock, from ethanolamines to fatty amines. Your purchase team raises one enquiry, compares one quote and manages one vendor record instead of six.
Different purities and supply forms of aminoethylethanolamine are available, so you are not forced to redesign a formulation around the only grade your supplier happens to carry.
COA, SDS, correct HSN and HS codes, transport declarations and certificates of origin are prepared with the consignment, not chased afterwards by your logistics team.
Tell us your limits on purity, related amines, water or colour and we quote against them, rather than sending the standard cut and letting your QC department find out.
Once we know your monthly draw we hold and release material on a schedule, so you carry less inventory than you otherwise would.
Describe the application rather than the product code and we will tell you which grade fits — and say so plainly when a different amine would serve you better.
Buyers who order aminoethylethanolamine usually source these from the same list. Open any product for its specification, grades and packing, or see the full product range.
Container shipments to buyers on five continents, plus road dispatch inside India. Tell us your country and destination port and we will quote landed terms, transit time and the documentation your customs broker will ask for.
United Arab Emirates, Saudi Arabia, Oman, Qatar, Kuwait, Bahrain, Jordan, Egypt, Morocco, Kenya, Tanzania, Ethiopia, Nigeria, Ghana and South Africa.
Bangladesh, Sri Lanka, Nepal, Pakistan, Vietnam, Thailand, Indonesia, Malaysia, Singapore, the Philippines, South Korea, Japan, Taiwan, Australia and New Zealand.
Germany, the Netherlands, Belgium, France, Italy, Spain, Portugal, Poland, Czechia, the United Kingdom, Ireland, Türkiye, Russia, Ukraine, Kazakhstan and Uzbekistan.
United States, Canada, Mexico, Brazil, Argentina, Chile, Colombia, Peru, Ecuador and the Caribbean, shipped in UN-specification packaging with full DG documentation.
| Incoterms quoted | EXW, FOB, CFR, CIF and DAP, depending on your destination and preference |
| Load ports | Nhava Sheva (JNPT) and Mundra, with Chennai and Kolkata used for eastbound routings |
| Container options | Full container loads, and consolidated LCL shipments for smaller quantities |
| Typical container fill | Around 80 drums of 200 kg, or roughly 18 to 20 IBC totes, in a 20 ft container |
| Packing for export | UN-specification drums and totes, palletised, strapped and stretch-wrapped, with DG labelling |
| Air freight | Possible for small quantities, within dangerous goods limits where the product is classified |
| Payment terms | Advance, irrevocable letter of credit or agreed credit terms for established accounts |
| Before first shipment | Company credentials, end-use declaration and any import permit the destination country requires |
Most delays in quoting aminoethylethanolamine come from a missing line in the enquiry, not from availability. Send these eight details and a firm price usually comes back the same day.
Not sure of some of it yet? Send what you have. A description of the application and an approximate monthly volume is enough for us to come back with a recommended grade, a pack plan and an indicative price.
Send an enquiryPlain definitions of the words that appear on a aminoethylethanolamine specification, label and shipping document.
Short answers to what purchase, plant and QC teams ask us most about this product. Anything else, ask us directly.
Send the grade, quantity, pack size and your delivery address or destination port. We come back with a price, the documents that go with the batch and a dispatch or shipping plan, usually within 24 hours.