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Allylamine (CAS 107-11-9) Supplier | Chelora Amines
AGlossary

Allylamine

Prop-2-en-1-amine · 3-Aminopropene · 2-Propen-1-amine

CAS107-11-9 Aliphatic amine C3H7N · 57.09 g/mol

The simplest unsaturated primary amine — a mobile, strongly ammoniacal liquid carrying both an amine and a vinyl group. That double handle is what makes it a building block for antifungal actives, cationic polymers and agrochemicals. Supplied by Chelora Amines in drums and bulk with COA and SDS.

Identification
CAS number107-11-9
EC / EINECS number203-463-9
MDL numberMFCD00008199
Molecular formulaC3H7N
Molecular weight57.09 g/mol
FamilyAliphatic amine
HS code2921.19
Physical properties
AppearanceColourless to pale yellow mobile liquid
OdourStrong ammoniacal; lachrymator
Melting point−88 °C
Boiling point53–58 °C
Flash point−29 °C (closed cup)
Density0.761 g/mL at 20 °C
Solubility in waterMiscible

What allylamine is

Allylamine is made industrially from allyl chloride and ammonia, and behaves as a typical strong primary amine while keeping the allyl double bond free for addition, polymerisation and metal-catalysed coupling. Both reactive sites in one small molecule are the reason it appears so often as a first step in multi-stage synthesis.

It is volatile, air sensitive and highly flammable, so it is normally handled in closed systems under nitrogen. Vapour is heavier than air and will travel to a distant ignition source, which drives most of the storage rules below.

Where it is used

Pharmaceutical intermediates

Route into the allylamine class of antifungals, including terbinafine, and many N-allyl building blocks.

Polyallylamine

Monomer for cationic polymers used in water treatment, paper retention aids and flocculation.

Agro & rubber chemicals

Intermediate for crop-protection actives, vulcanisation accelerators and corrosion inhibitors.

Surface chemistry

Plasma-polymerised allylamine films used to amine-functionalise biomaterials and membranes.

PARAMETERTYPICAL VALUEMETHOD
AppearanceClear colourless liquidVisual
Assaymin. 99.0 %GC
Water contentmax. 0.3 %Karl Fischer
Colourmax. 20 APHAPt–Co
Density at 20 °C0.758 – 0.764 g/mLPycnometer
Refractive index1.419 – 1.421n20/D

Typical values only — batch figures are stated on the certificate of analysis. Custom specifications on request.

Handling, packing and shipping

  • Highly flammable — flash point −29 °C. No open flames, sparks or smoking; use explosion-proof equipment and earthed transfer lines.
  • Toxic by inhalation, ingestion and skin absorption; causes serious skin and eye burns. Symptoms after inhalation may be delayed.
  • Vapour is heavier than air and can travel to a remote ignition source and flash back.
  • Reacts violently with strong oxidising agents and acids; store away from both.
  • Keep cool, dark and under inert gas in tightly closed containers; harmful to aquatic life, so keep out of drains.

Packing

180 kg MS drums under nitrogen, ISO tanks for bulk movements, and 25 kg / 5 kg packs for pilot quantities. Small glass bottles available for laboratory use.

Transport: UN 2334, Allylamine, Class 6.1 with subsidiary risk 3, PG I. Ships only on approved packaging against the current SDS.

Common questions

What is the CAS number of allylamine?

Allylamine is registered under CAS number 107-11-9, EC number 203-463-9, with the molecular formula C3H7N and a molecular weight of 57.09 g/mol.

What is allylamine used for?

It is an intermediate rather than an end product — mainly for allylamine antifungal actives such as terbinafine, for polyallylamine cationic polymers used in water treatment and papermaking, and for agrochemical and rubber-chemical synthesis.

Is allylamine flammable?

Yes. Its flash point is around −29 °C, so vapour-air mixtures are explosive at room temperature. It must be handled in closed systems with explosion-proof equipment and stored away from all ignition sources.

Is allylamine soluble in water?

It is miscible with water in all proportions and also dissolves in common alcohols and ethers, so aqueous and alcoholic process systems are both workable.

How is allylamine packed and shipped?

Chelora Amines supplies allylamine in 180 kg MS drums under nitrogen and in ISO tanks for bulk volumes, classified as UN 2334, Class 6.1 (3), PG I, with a certificate of analysis and safety data sheet on every despatch.

CAS NUMBERCHEMICAL NAMEFAMILY
96-20-8
2-Amino-1-butanol
AB, 2-AB
Alkanolamine View product
156-87-6
3-Amino-1-propanol
Propanolamine
Alkanolamine View product
616-30-8
3-Amino-1,2-propanediol
Aminopropanediol
Alkanolamine View product

See all 36 chemicals under A · 333 chemicals in the full glossary

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